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Preheat oven to 200°C.
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Place the olive oil in a large casserole dish, rub the chicken thighs in the olive oil and season them with the ground black pepper and dried mixed herbs, cover and bake for about 16 minutes, turning half way through. Check that the chicken is cooked through.
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Take the chicken out of the casserole dish and set aside to cool. Once it has cooled, shred the chicken with two forks.
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In the meantime, prepare the vegetables.
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Then place the onions and garlic in the casserole dish with the excess olive oil and chicken juices and return to the oven for about 6 minutes until the onion is soft.
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Add the carrots, celery, potatoes, rosemary, turmeric, paprika, barley, chicken broth and boiling water and bake, covered for 20 minutes. Now add the shredded chicken and bake, uncovered for another 20 minutes until the barley and potatoes are tender. Season to taste.
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Scatter over the kale, and serve.